期刊
CATALYSIS TODAY
卷 98, 期 1-2, 页码 99-108出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.cattod.2004.07.024
关键词
NiMo catalyst; hydrodesulfurization; alumina magnesia; characterization; textural stability
In the search to obtain stable catalysts for selective elimination of sulfur from gasoline, maintaining octane number, NiMo catalysts supported on Al-Mg mixed oxides were prepared by the sot-gel method and evaluated after 6-month storage in contact with ambient air, the results were compared with the freshly prepared samples. Both, freshly prepared and aged samples were characterized by nitrogen physisorption measurements (S-BET), infrared spectroscopy (FT-IR) and X-ray powder diffraction (XRD) and high-resolution electron microscopy (HREM), they were tested in the thiophene hydrodesulfurization reaction. The results indicate that the incorporation of small amounts of magnesia (5 mol%) into the alumina support, leads to the catalyst with low hydrogenation function and appropriate stability during prolonged contact with ambient conditions. (C) 2004 Elsevier B.V. All rights reserved.
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