期刊
APPLIED CATALYSIS A-GENERAL
卷 276, 期 1-2, 页码 251-255出版社
ELSEVIER
DOI: 10.1016/j.apcata.2004.08.011
关键词
dehydration; crude methanol; dimethyl ether (DME); surface acidity
A series of Na-modified H-ZSM-5 catalysts, with Na content varying from 0 to 80 mol%, were prepared by an impregnation method, characterized by TPD of ammonia and FT-IR pyridine methods, and tested for the dehydration of crude methanol (i.e. pure/anhydrous methanol containing 20 mol% of H2O) in a fixed-bed micro-reactor under normal atmospheric pressure. Though the unmodified H-ZSM-5 catalyst was more active and stable in the presence of water than the commercial gamma-Al2O3, the Na-modified H-ZSM-5 catalysts showed the optimum activity (C-MeOH > 80%) and 100% selectivity for DME in a wide range of temperatures: 230-340 degreesC. The catalysts were tested for the time-on-stream (TOS) and remained least sensitive towards water for a total reaction period of 65 h. The superior performance of Na-modified H-ZSM-5 catalyst is attributed mainly to the elimination of strong surface acid-sites by partial substitution of Na in H-ZSM-5, resulting in the prevention of coke and/or hydrocarbon formation. (C) 2004 Elsevier B.V. All rights reserved.
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