期刊
JOURNAL OF ORGANOMETALLIC CHEMISTRY
卷 689, 期 24, 页码 4055-4082出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2004.07.054
关键词
palladium; palladacycle; catalysis; cross-coupling; pincer; Heck reaction
The application of palladacycles as catalysts for cross-coupling and similar reactions is reviewed. In the majority of cases palladacycles are likely to serve as a source of highly active but unstable zero-valent palladium species. In this respect the palladacycles resemble the so-called phosphine-free catalysts. The advantages and limitations of palladacycle catalysts are discussed. (C) 2004 Elsevier B.V. All rights reserved.
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