4.6 Article

Multiferroic properties of layer-structured Bi5Fe0.5Co0.5Ti3O15 ceramics

期刊

APPLIED PHYSICS LETTERS
卷 95, 期 8, 页码 -

出版社

AMER INST PHYSICS
DOI: 10.1063/1.3213344

关键词

bismuth compounds; calcination; ceramics; cobalt compounds; Curie temperature; ferromagnetic materials; iron compounds; magnetic moments; multiferroics

资金

  1. Chinese National Natural Science Foundation [10274066]
  2. Jiangsu Province Department of Education [08KJB140011]
  3. U. S. Air Force Office of Scientific Research (AFOSR)
  4. U. S. Air Force Research Laboratories (AFRL)

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Layer-structured, single phase Bi5Fe0.5Co0.5Ti3O15 ceramics was synthesized following a multicalcination procedure. Magnetic moment increases more than three times by substituting half Fe sites by Co ions. The material exhibits an Aurivillius phase with a four-layer unit cell structure, and presents a remarkable coexistence of ferroelectricity and ferromagnetism above room temperature. The measured 2P(r) and 2M(r) are 13 mu C/cm(2) and 7.8 memu/g, respectively. The material's magnetic behavior below 275 degrees C is relaxationlike and its magnetic Curie temperature is similar to 345 degrees C.

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