A crucial goal for modern telecommunications systems is development of very high-speed components for broadband (> 100 GHz), all-optical signal/information processing. The core component of such technologies is the electro-optic modulator, which encodes electrical signals onto fibre-optic transmissions. A significant challenge therefore is obtaining materials that have large electro-optic responses and that can be readily fabricated into devices at low cost. We report here on the realization of high-response heteroaromatic organic chromophores that can be straightforwardly self-organized from the vapour phase into intrinsically acentric, high-quality, micrometre-scale films. These pi-conjugated electrooptically active films (with second-order susceptibilities up to similar to 100 pm V-1) are thermally stable and conveniently grown by a simple physical vapour deposition process in a few hours. Supramolecular acentricity is achieved without electric field poling, enforced by biomimetic heterocycle hydroxycarbonyl head-to-tail hydrogen-bonding.
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