4.6 Article

The colossal magnetocaloric effect in Mn1-xFexAs: What are we really measuring?

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APPLIED PHYSICS LETTERS
卷 95, 期 7, 页码 -

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AMER INST PHYSICS
DOI: 10.1063/1.3194144

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entropy; ferromagnetic materials; iron compounds; magnetocaloric effects; manganese compounds; Maxwell equations

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Recently, a so-called colossal magnetocaloric effect (MCE) was reported in Mn1-xFexAs [A. de Campos , Nat. Mater. 5, 802 (2006)]. However, the value of Delta S that was determined appears markedly overestimated since it results from the inadequate use of the Maxwell relation. Here, we report on recent measurements of Delta S in Mn1-xFexAs from which a correct MCE value is deduced by using the Clausius-Clapeyron equation. This result is asserted by careful use of the Maxwell relation.

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