期刊
APPLIED PHYSICS LETTERS
卷 95, 期 6, 页码 -出版社
AMER INST PHYSICS
DOI: 10.1063/1.3204006
关键词
contact angle; hydrophobicity; organic compounds; surface roughness; water
资金
- BASF Electronic Materials Taiwan Ltd
- National Science Council of Taiwan [98-2221-E-008-051MY3, 98-2221-E-002-085]
A typical superhydrophobic surface is essentially nonadhesive and exhibits very low water contact angle (CA) hysteresis, so-called Lotus effect. However, leaves of some plants such as scallion and garlic with an advancing angle exceeding 150 degrees show very serious CA hysteresis. Although surface roughness and epicuticular wax can explain the very high advancing CA, our analysis indicates that the unusual hydrophobic defect, diallyl disulfide, is the key element responsible for contact line pinning on allium leaves. After smearing diallyl disulfide on an extended polytetrafluoroethylene (PTFE) film, which is originally absent of CA hysteresis, the surface remains superhydrophobic but becomes highly adhesive.
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