期刊
APPLIED PHYSICS LETTERS
卷 94, 期 10, 页码 -出版社
AMER INST PHYSICS
DOI: 10.1063/1.3099804
关键词
annealing; antimony alloys; cerium alloys; cobalt alloys; doping; grain size; indium alloys; nanostructured materials; phonons; plasma materials processing; quenching (thermal); sintering; thermal conductivity; thermoelectricity
资金
- National Basic Research Program of China [2007CB607501]
- National Science Foundation of China [50731006]
- 111 Project of China [B07040]
n-Type skutterudites InxCeyCo4Sb12 with in situ forming nanostructured InSb phase have been prepared by a melt-quench-anneal-spark plasma sintering method. Doping of In results in a nanostructured InSb phase with the grain size of 10-80 nm that is evenly distributed on the boundaries of the skutterudite matrix. The nanostructured InSb phase has a strong influence on phonon scattering and leads to a notable suppression of the lattice thermal conductivity of InxCeyCo4Sb12. The combined effect of In and Ce doping results in high performance skutterudite materials. The highest thermoelectric figure of merit ZT=1.43 is achieved at 800 K in the In0.2Ce0.15Co4Sb12 compound.
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