期刊
JOURNAL OF NUCLEAR MATERIALS
卷 335, 期 3, 页码 302-310出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jnucmat.2004.05.010
关键词
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Single-phase magnesium-nickel ferrites with varying amounts of nickel and magnesium were characterized by X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) techniques. A plot of lattice parameter versus composition of the ferrites (MgxNi(1-x)Fe2O4, x less than or equal to 1) showed an abrupt deviation of lattice parameter linearity near MgFeO4. The deviation was explained in terms of the distribution of Mg2+ in the octahedral and tetrahedral sites of the oxygen lattice. In XPS spectra, a broadening of the Mg 1s peak in Ni rich Mg-Ni ferrites from that observed in pure MgFe2O4, was explained by changes in the distribution of Mg2+ ion in tetrahedral and octahedral sites. A depth distribution of Mg in Ni0.5Mg0.5Fe2O4 showed an enrichment of Mg on surface. (C) 2004 Elsevier B.V. All rights reserved.
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