Comparison of effective transverse piezoelectric coefficients e31,f of Pb(Zr,Ti)O3 thin films between direct and converse piezoelectric effects

We evaluated the effective transverse piezoelectric coefficients (e(31,f)) of Pb(Zr,Ti)O-3 (PZT) thin films from both the direct and converse piezoelectric effects of unimorph cantilevers. (001) preferentially oriented polycrystalline PZT thin films and (001)/(100) epitaxial PZT thin films were deposited on (111)Pt/Ti/Si and (001)Pt/MgO substrates, respectively, by rf-magnetron sputtering, and their piezoelectric responses owing to intrinsic and extrinsic effects were examined. The direct and converse vertical bar e(31,f)vertical bar values of the polycrystalline PZT thin films were calculated as 6.4 and 11.5-15.0C/m(2), respectively, whereas those of the epitaxial PZT thin films were calculated as 3.4 and 4.6-4.8C/m(2), respectively. The large vertical bar e(31,f)vertical bar of the converse piezoelectric property of the polycrystalline PZT thin films is attributed to extrinsic piezoelectric effects. Furthermore, the polycrystalline PZT thin films show a clear nonlinear piezoelectric contribution, which is the same as the Rayleigh-like behavior reported in bulk PZT. In contrast, the epitaxial PZT thin films on the MgO substrate show a piezoelectric response owing to the intrinsic and linear extrinsic effects, and no nonlinear contribution was observed. (C) 2015 The Japan Society of Applied Physics