4.6 Article

Stable nitride complex and molecular nitrogen in N doped amorphous Ge2Sb2Te5

期刊

APPLIED PHYSICS LETTERS
卷 93, 期 24, 页码 -

出版社

AMER INST PHYSICS
DOI: 10.1063/1.3052046

关键词

ab initio calculations; amorphous semiconductors; annealing; antimony compounds; germanium compounds; molecular dynamics method; nitrogen; phase change materials; semiconductor thin films

资金

  1. Nature Science Foundation of Fujian Province of China [2008J0166]
  2. Xiamen University [X071I4]

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Nitrogen doping is identified to be a sufficient way to reduce the power consumption of Ge2Sb2Te5, a phase-change material for data storage. On the basis of ab initio molecular dynamics simulations, we show that the doped N in amorphous Ge2Sb2Te5 coexist as Ge(Sb, Te)N complex and N-2, and high density of the film produces more N-2. Furthermore, both Ge(Sb, Te)N complex and N-2 are stable upon annealing at 600 K.

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