期刊
CHEMISTRY OF MATERIALS
卷 16, 期 25, 页码 5502-5511出版社
AMER CHEMICAL SOC
DOI: 10.1021/cm040132h
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Stable (c) and metastable (h) forms Of Mg2Sn were prepared as crystallized phases by ball-milling of elemental powders. Through in situ X-ray diffraction measurements, we deduced the reactivity mechanisms Of c-Mg2Sn toward lithium. It entails first a monophasic insertion of about one lithium per formula unit into the fcc Sn framework without extrusion of either Mg or Sn, then a biphasic process leading to the formation of cubic Li2MgSn concomitant with a progressive expulsion of Mg, and finally the formation of Li-Mg solid-solution alloys. Upon charging, the poor reversibility of the alloying reaction of Li with Mg leads to a deficit in free Mg, resulting in the formation of a Mg2Sn + Sn mixture, and accounting for the poor cyclability Of Mg2Sn/Li cells over the 0.0-1.5 V voltage window. Limiting the cycling to the monophasic process was shown to improve the cycling behavior. Finally, we found that the electrochemical reaction of h-Mg2Sn with Li leads to the same Li2MgSn intermediate and the same subsequent sequence of transformations, resulting in similarly poor capacity retention upon cycling.
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