期刊
JOURNAL OF PHYSICS-CONDENSED MATTER
卷 16, 期 49, 页码 L499-L504出版社
IOP PUBLISHING LTD
DOI: 10.1088/0953-8984/16/49/L01
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Recent experimental data for the centrifugal sedimentation-diffusion profile of charged colloidal silica (phi similar to 44 nm) in ethanol is analysed based on local charge neutrality and by either assuming a fixed particle charge or incorporating charge regulation. Especially at a high Debye length ( > 30 nm) the two models deviate at higher particle volume fractions phi ( > 0.1 vol%) with the data much better reproduced when charge regulation is included.
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