期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 126, 期 49, 页码 16179-16186出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja046289s
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Chiral fluorescent boronic acid 1 was found to be a highly enantioselective, chemoselective, and sensitive sensor for sugar acids, such as tartaric acid. Enantioselectivities (K-R/K-S) of up to 550:1, chemoselectivity up to 11000:1, and sensitivities in the micromolar range with sensor 1 were observed. Single-crystal X-ray analysis was used to confirm the structure of the fluorescent species.
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