期刊
JOURNAL OF PHYSICAL CHEMISTRY B
卷 108, 期 50, 页码 19384-19387出版社
AMER CHEMICAL SOC
DOI: 10.1021/jp046857q
关键词
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Nitrogen-doped titania photocatalysts were prepared from titanium tetraisopropoxide or titanium tetrachloride and thiourea. The yellow powders obtained after calcination at 400-600 degreesC photocatalyze the mineralization of 4-chlorophenol by visible light (lambda greater than or equal to 455 nm). Different from previously published data these materials do not contain sulfur but instead nitrogen as the doping component inducing visible light photocatalysis. The measured band gap narrowing of 40-80 meV and the anodic shift of the quasi Fermi potential of 40-90 mV are in agreement with recent results on nitrogen-doped titania.
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