期刊
SYNTHESIS-STUTTGART
卷 -, 期 18, 页码 2943-2958出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-2004-834932
关键词
asymmetric catalysis; asymmetric hydrosilylation; chiral ligands; rhodium; titanium; zinc; conjugate addition; reduction
This literature review focuses on the recent advances in the asymmetric hydrosilylation of ketones and imines. New catalyst systems based on various transition metals, such as rhodium, titanium, zinc, copper and tin, combined with classical or new ligand structures, are presented. These systems lead to very effective and selective protocols for the reduction of prochiral ketones, imines and electrophilic double bonds.
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