期刊
ORGANIC LETTERS
卷 6, 期 26, 页码 5019-5021出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol0477273
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资金
- NIGMS NIH HHS [R01 GM025521-21, R01 GM025521-20, R01 GM025521-25, GM 25521, R01 GM025521-24, R01 GM025521-26, R01 GM025521-23, R01 GM025521-22] Funding Source: Medline
Type II isopentenyl diphosphate:dimethylallyl diphosphate (IPP:DMAPP) isomerase from Synechocystis PCC 6803 catalyzes the interconversion of IPP and DMAPP. Upon incubation of the enzyme with IPP or DMAPP in (H2O)-H-2, one deuterium is incorporated into the C2 methylene of IPP, two deuteriums are incorporated at C4, and three deuteriums are incorporated into the (E)-methyl of DMAPP.
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