期刊
MOLECULAR PHYSICS
卷 103, 期 1, 页码 99-104出版社
TAYLOR & FRANCIS LTD
DOI: 10.1080/00268970412331303341
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Self-adapting fixed endpoint configurational-bias Monte Carlo simulations in the Gibbs ensemble were carried out to determine the vapour-liquid coexistence curves of cyclic alkanes from c-pentane to c-octadecane. In general, the critical temperatures and densities of the cyclic alkanes are substantially higher than those of their linear counterparts. Furthermore, the simulation data point to a maximum in the critical density for cyclic alkanes with about eight carbon atoms as also observed for the linear alkanes.
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