期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 127, 期 1, 页码 210-216出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja0471525
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资金
- NIGMS NIH HHS [GM28384] Funding Source: Medline
Huisgen's 1,3-dipolar cycloadditions become nonconcerted when copper(l) acetylides react with azides and nitrile oxides, providing ready access to 1,4-disubstituted 1,2,3-triazoles and 3,4-disubstituted isoxazoles, respectively. The process is highly reliable and exhibits an unusually wide scope with respect to both components. Computational studies revealed a stepwise mechanism involving unprecedented metallacycle intermediates, which appear to be common for a variety of dipoles.
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