期刊
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
卷 61, 期 3, 页码 509-514出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.saa.2004.04.026
关键词
vibrational spectra; 6-nitrochrysene; Raman spectra
类别
The infrared and Raman spectra of solids and thin solid films of 6-nitrochrysene, its electronic spectra, and resonance Raman scattering (RRS) obtained with UV-Iaser excitation at 325 nm are reported. The vibrational assignment is supported by ab initio computations at the B3LYP/6-31 1G(d, p) level of theory. The molecular organization in nanometric films evaporated onto smooth metal surfaces of silver and copper was probed using reflection-absorption infrared spectroscopy (RAIRS). The results of the surface-enhanced Raman scattering (SERS) and surface-enhanced infrared absorption (SEIRA) obtained from nanometric films evaporated onto silver island films are also discussed. It was found that the molecule efficiently interacts with silver island film surfaces, and that the interaction leads to extensive photochemical reaction at the metal surface under laser illumination. (C) 2004 Elsevier B.V. All rights reserved.
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