期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 70, 期 2, 页码 707-708出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo048509q
关键词
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Pyrene and 2,7-disubstituted pyrenes have been oxidized with ruthenium(III) chloride (RuCl3) and sodium periodate (NaIO4) under very mild conditions to 4,5-diones or 4,5,9,10-tetraones. Thus, the oxidation has been controlled by varying the amount of oxidant and reaction temperature to proceed exclusively at the pyrene 4- and 5-positions or at the 4-, 5-, 9-, and 10-positions.
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