期刊
APPLIED PHYSICS EXPRESS
卷 5, 期 4, 页码 -出版社
JAPAN SOC APPLIED PHYSICS
DOI: 10.1143/APEX.5.042303
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资金
- Core Research for Evolutional Science and Technology (CREST) of the Japan Science and Technology Agency
This study explores a new factor affecting the performance of dye-sensitized solar cells in the presence of 4-tert-butylpyridine (TBP) by elucidating interactions between TBP and Ru(H(2)dcbpy)(2)(NCS)(2) (N3 dye; H(2)dcbpy = 2,2'-bipyridyl-4,4'-dicarboxylic acid). Combining experimental and computational studies, we reveal that these interactions result from the formation of a hydrogen bond between the oxygen atom of carboxylate groups of the N3 dye and the hydrogen atom of the N-containing heterocycle of TBP. The effects of interactions between TBP and the N3 dye on J(sc) are also discussed. (C) 2012 The Japan Society of Applied Physics
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