期刊
ACCOUNTS OF CHEMICAL RESEARCH
卷 38, 期 2, 页码 137-145出版社
AMER CHEMICAL SOC
DOI: 10.1021/ar040106p
关键词
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Optical devices based on polymer-dispersed liquid crystal (PDLC) thin films derive their functional properties from the electric-field-induced reorientation of (sub)micrometer-sized polymer-dispersed liquid crystal (LC) droplets. In these materials, the LC reorientation dynamics are strongly dependent on droplet size and shape, as well as polymer/LC interfacial interactions. The dynamics also vary spatially within individual droplets. This Account describes studies of individual PDLC droplets and their field-induced dynamics by high-resolution near-field scanning optical microscopy (NSOM) and multiphoton-excited fluorescence microscopy (MPEFM). Included are studies of native (pure) PDLCs and those doped with ionic compounds and dyes; the latter are used in sophisticated photorefractive materials.
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