期刊
SYNLETT
卷 -, 期 2, 页码 328-330出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-2004-836065
关键词
TAN1251 alkaloid; total synthesis; aromatic oxidations; hypervalent iodine; spiro cyclization
An enantiospecific total synthesis of TAN1251C and TAN1251D has been achieved. An aromatic oxidation reaction of a secondary amine, which is prepared from two molecules of L-tyrosine derivatives, with hypervalent iodine reagent gave a spirocyclic product as a key intermediate for the synthesis of TAN 1251C and D.
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