期刊
APPLIED PHYSICS B-LASERS AND OPTICS
卷 101, 期 3, 页码 631-638出版社
SPRINGER
DOI: 10.1007/s00340-010-4199-z
关键词
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资金
- FAPESP, Brazil
The Er3Al5O12 phosphor powders were prepared using the solution combustion method. Formation and homogeneity of the Er3Al5O12 phosphor powders have been verified by X-ray diffraction and energy-dispersive X-ray analysis respectively. The frequency up-conversion from Er3Al5O12 phosphor powder corresponding to the H-2(9/2) -> I-4(15/2), H-2(11/2) -> I-4(15/2), S-4(3/2) -> I-4(15/2), F-4(9/2) -> I-4(15/2) and the infrared emission (IR) due to the I-4(13/2) -> I-4(15/2) transitions lying at similar to 410, similar to 524, similar to 556, 645-680 nm and at similar to 1.53 mu m respectively upon excitation with a Ti-Sapphire pulsed/CW laser have been reported. The mechanism responsible for the frequency up-conversion and IR emission is discussed in detail. Defect centres induced by radiation were studied using the techniques of thermoluminescence and electron spin resonance. A single glow peak at 430A degrees C is observed and the thermoluminescence results show the presence of a defect center which decays at high temperature. Electron spin resonance studies indicate a center characterized by a g-factor equal to 2.0056 and it is observed that this center is not related to the thermoluminescence peak. A negligibly small concentration of cation and anion vacancies appears to be present in the phosphor in accordance with the earlier theoretical predictions.
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