One-step synthesis of flower-like Au-ZnO microstructures at room temperature and their photocatalytic properties

In this paper, 3D flower-like Au-ZnO microstructures with controlled morphology and dimensions were synthesized by a facile one-step aqueous solution route at room temperature, and the photocatalytic properties of these structures were investigated. The as-prepared flower-like Au-ZnO structures with a diameter of about 3 mu m consisted of many ZnO nanosheets which interacted with each other. These nanosheets, which were successfully decorated by Au NPs, showed an average thickness of 10 nm and a single-crystalline structure with {2-1-10} planar surfaces. The growth process of Au-ZnO structures and the effects of trisodium citrate on the nucleation and growth of ZnO were investigated. The formation of Au NPs in this experiment was discussed too. The Au-ZnO structures showed higher photocatalytic activity than that of pure ZnO.