期刊
MACROMOLECULAR RAPID COMMUNICATIONS
卷 26, 期 3, 页码 160-163出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.200400477
关键词
cationic ring-opening polymerization; microwave; 2-phenyl-2-oxazoline; poly(N-benzoylethylenimine)
We studied the cationic ring-opening polymerization of 2-phenyl-2-oxazoline under microwave irradiation. A comparison with thermal heating shows a great enhancement in the reaction rates while the living character of the polymerization is conserved. The polymerizations were performed at the temperature of boiling butyronitrile (123degrees). The polymerization of 2-phenyl-2-oxazoline under microwave conditions, described herein for the first time, is shown to be a rapid and environmentally friendly alternative to the classical methods.
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