4.6 Article

Large electrostrictive strain in lead-free Bi0.5Na0.5TiO3-BaTiO3-KNbO3 ceramics

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SPRINGER
DOI: 10.1007/s00339-010-6074-5

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  1. Science and Technology Commission of Shanghai Municipality [10ZR1422300, 09520501000]
  2. Shanghai Municipal Education Commission [09YZ151]
  3. Shanghai Normal University [SK200708]
  4. National Natural Science Foundation of China [60807036]
  5. Natural Science Foundation of Ningbo [2009A610103]
  6. Condensed Physics of Shanghai Normal University [DZL712]

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In the present work, (1-x)(0.935Bi(0.5)Na(0.5)TiO(3)-0.065BaTiO(3))-xKNbO(3) (BNT-BT-KN, BNT-BT-100xKN) ceramics with x ranging from 0 to 0.1 were prepared by the conventional ceramic fabrication process. A large electrostrictive coefficient of similar to 10(-2) m(4) C-2 is obtained with the composition x ranging from 0.02 to 0.1, which is close to the well-known electrostrictive material Pb(Mg1/3Nb2/3)O-3. Under an electric field of 4 kV/mm, the electrostrictive strain can reach as high as 0.08%. Besides, the electric field induced strain behavior indicates a temperature independent behavior within the temperature range of 20 to 150A degrees C. The large electrostrictive strain is suggested to be ascribed to the formation of non-polar (NP) phase developed by the KNbO3 substitution, and the high electrostrictive coefficient of BNT-BT-KN ceramics makes them great candidates to be applied in the new solid-state actuators.

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