期刊
INORGANICA CHIMICA ACTA
卷 358, 期 3, 页码 520-526出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ica.2004.09.059
关键词
Cu-complexes; Zn-complexes; modular assembly; hydrogen bonding
The strong affinity of coordinated biimidazole for chloride ion via N-(HCl-)-Cl-... hydrogen bonding has been used as a strategy to build up two different modular assemblies between chloride and biimidazole-metal modules. The crystal structure of these two new metal-containing architectures, {[Cu(H(2)biim)(2)]Cl-2 (1) and [Zn(Cl)(H(2)biim)(2)]Cl (2)}, is reported. The EPR spectrum of 1 is also discussed. (C) 2004 Elsevier B.V. All rights reserved.
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