期刊
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
卷 226, 期 2, 页码 227-230出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.molcata.2004.10.031
关键词
propyne; propene; hydrogenation; carbon-supported palladium catalyst; kinetic discontinuity
The hydrogenation of propyne over a 1 wt.% Pd/C catalyst that has previously been shown to exhibit a kinetic discontinuity effect for this reaction has been studied under conditions below the transition point to evaluate the characteristics that permit dramatic changes in conversion and selectivity as a function of hydrogen concentration. (C) 2004 Elsevier B.V All rights reserved.
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