期刊
JOURNAL OF PHYSICAL CHEMISTRY B
卷 109, 期 6, 页码 2439-2444出版社
AMER CHEMICAL SOC
DOI: 10.1021/jp040236f
关键词
-
Analysis of photocatalyst kinetics to date have relied largely on Langmuir-Hinshelwood rate forms, which assume equilibrated adsorption of reactants and, correspondingly, a slow, rate-controlling surface step. Alternatively, and more generally, a pseudo-steady state analysis based upon the stationary state hypothesis for reaction intermediates may be applied. We show here that only this second approach is consistent with the reported intensity dependence of apparent adsorption (and desorption) binding constants, as well as the catalytic rate constant. In consequence, we show that for at least some photocatalyzed reactions, adsorption/desorption reaction equilibria are not established during reaction, because the substantial reactivity of an adsorbed active species (e.g., hole (h+), radical (*OH), etc.) causes a continued displacement from equilibrium of the adsorbed reactant concentration.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据