期刊
ORGANIC LETTERS
卷 7, 期 4, 页码 621-623出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol047634l
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资金
- NIGMS NIH HHS [GM 57870] Funding Source: Medline
The asymmetric synthesis of the cytotoxic marine metabolite (-)-agelastatin A (1) has been achieved from the C-ring intermediate 4,5-diamino cyclopenten-2-enone (-)-2. This key intermediate was efficiently prepared from the sulfinimine-derived alpha,beta-diamino ester 4 using ring-closing metathesis.
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