期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 70, 期 4, 页码 1204-1210出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo048137l
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[GRAPHICS] The first C-3v- and D-3h-symmetrical triply bridged calix[6]azatubes were prepared in good yields from the known 1,3,5-tris-methylated calix[6]arene through an efficient [1 + 1] macrocyclization reaction. A remarkably regioselective hexa ipso-nitration reaction led to a calix [6]azatube substituted at the wide rim in alternate position by tBu and nitro groups. A H-1 NMR study showed that, whereas the parent bis-calix[6]arenes self-include their methoxy groups, thereby closing their inner tube, the nitro-substituted calix[6]azatube undergoes a conformational change with the expulsion of the methoxy groups, hence presenting a three-dimensional structure open for host-guest applications.
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