4.4 Article

Tetracyanoethylene oxide not only oxidizes sulfides to sulfoxides but also reduces sulfoxides to sulfides

期刊

TETRAHEDRON LETTERS
卷 46, 期 9, 页码 1395-1397

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2005.01.057

关键词

oxidation and reduction; sulfur ylide; carbonyl cyanide; sulfide; sulfoxide

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It was found that tetracyanoethylene oxide not only oxidizes sulfides to sulfoxides but also reduces sulfoxides to sulfides with generation of two molecules of carbonyl cyanide. The reaction thus also functions as a new method for generation of carbonyl cyanide. (C) 2005 Elsevier Ltd. All rights reserved.

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