期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 347, 期 4, 页码 591-594出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200404308
关键词
homogeneous catalysis; N-heterocyclic carbenes; ruthenium; transfer hydrogenation
资金
- Engineering and Physical Sciences Research Council [GR/S41630/01] Funding Source: researchfish
The dihydride ruthenium N-heterocyclic carbene complex Ru(IMes)(PPh3)(2)CO(H)(2) (1) (IMes = 1,3-dimesityl-1,3-dihydro-2H-imidazol-2-ylidene) is an efficient catalyst for both direct hydrogenation and transfer hydrogenation of ketones and imines, in the absence of base.
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