期刊
APPLIED ORGANOMETALLIC CHEMISTRY
卷 32, 期 11, 页码 -出版社
WILEY
DOI: 10.1002/aoc.4539
关键词
metal organic frameworks; Mizoroki-Heck reaction; open metal site MOF; Pd-II@Cu (BDC); 2-Py-SI
Palladium ions were successfully immobilized within the pores of open metal site (OMS) metal organic frameworks (MOFs) with Schiff-base (2-Py-SI) grafted in OMS-Cu (BDC) using the hydrothermal method. This Schiff-base complex on the Cu (BDC) greatly increased catalytic activity and acted as an efficient stabilizer of Pd ions. The hydrothermal method was a more efficient method for generating small metal ions in the MOF structures. The results revealed that the Pd-II@Cu (BDC)/2-Py-SI is a promising catalyst for the Mizoroki-Heck coupling reaction. The proposed catalyst has better recyclability and can be reused several times without apparent loss of activity.
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