期刊
APPLIED ORGANOMETALLIC CHEMISTRY
卷 32, 期 12, 页码 -出版社
WILEY
DOI: 10.1002/aoc.4547
关键词
hydrogenation; mesoporous silica; nitriles; secondary and tertiary amines; supported aqueous-phase catalysts
资金
- NSERC of Canada
- FESR of Universite de Moncton
The first supported aqueous-phase catalyst for the hydrogenation of nitriles is revealed. The catalyst prepared from Pd(PhCN)(2)Cl-2, water-soluble ligand 2,2 '-biquinoline-4,4 '-dicarboxylic acid dipotassium salt and mesoporous silica is a highly efficient catalyst for the selective formation of secondary or tertiary amines from aromatic or aliphatic nitriles. The catalytic system is stable and can be recycled and reused three times without loss of activity and selectivity. This environmentally friendly process is, in addition, an attractive alternative to many homogeneous and heterogeneous catalysts because of its easy preparation and the moderate operational conditions under which it is highly active.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据