期刊
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY
卷 41, 期 3, 页码 352-357出版社
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1007/s11178-005-0169-z
关键词
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Cyclomagnesation of terminal and cyclic olefins and 1,2-dienes with RMgHlg and R2Mg in the presence of dichloro(dicyclopentadienyi)titanium(IV) gives non-Grignard cyclic and acyclic organornaanesium compounds. The reaction direction depends on the structure of unsaturated initial compound. The most probable reaction mechanism is discussed.
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