期刊
SCIENCE AND TECHNOLOGY OF ADVANCED MATERIALS
卷 6, 期 2, 页码 143-148出版社
IOP PUBLISHING LTD
DOI: 10.1016/j.stam.2004.11.006
关键词
photocatalyst; titanium dioxide; nitrogen doping; guanidine; visible light
In order to utilize visible light in photocatalytic reactions, nitrogen atoms were doped in commercially available photocatalytic TiO2 powders by using an organic compound such as urea and guanidine. Analysis by X-ray photoelectron spectroscopy (XPS) indicated that N atoms were incorporated into two different sites of the bulk phase of TiO2. A significant shift of the absorption edge to a lower energy and a higher absorption in the visible light region were observed. These N-doped TiO2 powders exhibited photocatalytic activity for the decomposition of 2-propanol in aqueous solution under visible light irradiation. The photocatalytic activity increased with the decrease of doped N atoms in O site, while decreased with decrease of the other sites. Degradation of photocatalytic activity based on the release of nitrogen atoms was observed for the reaction in the aqueous suspension system. (c) 2005 Elsevier Ltd. All rights reserved.
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