期刊
RUSSIAN CHEMICAL BULLETIN
卷 54, 期 3, 页码 684-690出版社
SPRINGER
DOI: 10.1007/s11172-005-0306-4
关键词
thiophenesilane dendrimers; organosilicon compounds; oligothiophenes; Kumada reaction; Suzuki reaction
The synthesis of tris {5'-[methylbis(2-thienyl)silyl]-2,2'-bithienyl-5-yl} methylsilane, a first-generation bithiophenesilane dendrimer, is described. The conditions of effective formation of methyltrithienylsilane were found; methyltris(5-bromo-2-thienyl)silane and a number of other monofunctional derivatives of methyltrithienylsilane were synthesized for the first time. The advantages and drawbacks of the Suzuki and Kumada reactions for the formation of bithienyl fragments in the synthesis of oligothienylsilane dendrimers are discussed.
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