期刊
INORGANIC CHEMISTRY COMMUNICATIONS
卷 8, 期 3, 页码 271-273出版社
ELSEVIER
DOI: 10.1016/j.inoche.2004.12.026
关键词
hydrothermal synthesis; indium phosphite; organic template; crystal structure
The first organically templated indium phosphite (H3NC2H4NH3)[In(OH)(3)(HPO3)] was hydrothermally synthesized and characterized by single crystal X-ray diffraction, the powder X-ray diffraction, thermogravimetric analysis and IR spectroscopy. The compound is built up from InO3(OH)(3) octahedron and HPO3 pseudo-pyramid that share vertices. The connectivity between InO3(OH)(3) and HPO3 units gives rise to a ladder-like chain architecture containing fused [In2P2O4] four-member rings. (C) 2005 Elsevier B.V. All rights reserved.
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