期刊
POLYMER
卷 46, 期 7, 页码 2047-2058出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.polymer.2005.01.034
关键词
thiophene; ionic-liquids; electropolymerisation
Thiophene, bithiophene and terthiophene have been electropolymerised using ionic liquids as the growth medium and the supporting electrolyte. Both imidazolium and pyrrolidinium-based ionic liquids were used to assess the influence of the nature of the ionic liquid on the morphology and electrochemical activity of the conducting polymers. The pyrrolidinium-based ionic liquid produced slightly smoother films for all the thiophene species studied. A number of the polymers displayed multiple redox peaks, the possible origins of which are discussed. Both the ionic liquid and the choice of monomer had a significant influence on the polymer produced. (c) 2005 Elsevier Ltd. All rights reserved.
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