期刊
INORGANICA CHIMICA ACTA
卷 358, 期 5, 页码 1386-1392出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ica.2004.06.068
关键词
gold(I) complexes; alkynyl complexes; ethynylanilines; x-ray crystal structure
Reaction of [AuCl(SMe2)] with para-ethynylaniline and para-ethynyl-ortho-toluidine affords oligomers, [Au(C equivalent to C-4-C6H3RNH2)L] (R = H, Me), which in turn react with tertiary phosphines or 2,5-dimethylphenylisocyanide to give monomeric adducts, [Au(C equivalent to C-4-C6H3RNH2)L]. One of these, [Au(C equivalent to C-4-C6H4NH2){P(3-tolyl)(3)}], has been crystallographically characterised and is a polymer in the solid state, being held together via (NHAu)-Au-. . . contacts. (c) 2004 Elsevier B.V. All rights reserved.
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