期刊
MACROMOLECULAR RAPID COMMUNICATIONS
卷 26, 期 6, 页码 461-466出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.200400529
关键词
clay; conducting polymers; intercalation; mechanochemical; polypyrroles
Non-ionic pyrrole was directly intercalated into unmodified montmorillonite (MMT) and organically modified MMT galleries by adsorption, and subsequently polymerized within the interlamellar spaces by a mechanochemical route under solvent-free conditions. XRD analysis revealed the successful intercalation of pyrrole into unmodified MMT and organically modified MMT clay galleries by mechanochemical grinding. After in situ polymerization, the XRD and FT-IR analyses confirmed the insertion of polypyrrole chains between both MMT galleries.
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