期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 70, 期 6, 页码 2329-2331出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo048144+
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Optically pure allylic amines have been synthesized from alpha,beta-unsaturated aldehydes via allylboration with (-)-B-allyldiisopinocampheylborane, followed by Overman rearrangement. By incorporating crotyl and alkoxyallylboration, functionalization at delta-position was readily accomplished. By applying this methodology, the synthesis of several chiral a.-amino acids has been achieved.
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