期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 70, 期 6, 页码 2335-2337出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo0480895
关键词
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Additions of lithium acetylides and n-BuLi to N-alkyl ketimines mediated by BF3-Et2O in THF afford hindered tert-alkylamines in moderate to good yields. Stereochemical results and crystal structures of three BF3-imine complexes suggest that allylic strain strongly influences conformation and may be an important determinant of reactivity and selectivity.
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