期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 347, 期 5, 页码 609-631出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200404232
关键词
asymmetric catalysis; hydroboration; P,N chiral ligands; P,P chiral ligands; mechanistic studies; rhodium
Rhodium-catalysed enantioselective hydroboration of olefins is a valuable synthetic transformation, typically employing a chiral catalyst and an achiral borane source. The pertinent chemo-, regio- and enantioselectivity issues of this reaction are discussed. However, the main emphasis of this review is on the evolution of catalytic asymmetric hydroboration. This has primarily relied upon the development and application of chiral bidentate PP and P,N ligands which have exhibited varying degrees of success in this transformation.
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