Density-functional simulations have been performed on Na-55, Na-92, and Na-142 clusters in order to understand the experimentally observed melting properties [M. Schmidt , Nature (London) 393, 238 (1998)]. The calculated melting temperatures are in excellent agreement with the experimental ones. The calculations reveal a rather subtle interplay between geometric and electronic shell effects, and bring out the fact that the quantum mechanical description of the metallic bonding is crucial for understanding quantitatively the variation in melting temperatures observed experimentally.
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