期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 347, 期 5, 页码 637-640出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200404381
关键词
allylic compounds; copper; cuprates; silicon; zinc
The first copper-catalyzed allylic substitution reactions of allylic acetates and carbamates employing a bis(triorganosilyl)zinc reagent are reported. This novel procedure avoids the use of stoichiometric amounts of copper salts which are usually mandatory with this chemistry. Application of this methodology to standard model substrates substantiates a high diastereoselectivity for the double bond geometry (E: Z) as well as the relative configuration (syn: anti).
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