期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 347, 期 5, 页码 703-705出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200404315
关键词
C-H activation; homogeneous catalysis; hydrogen peroxide; iron; oxidation
An iron-catalyzed process for the oxidation of saturated hydrocarbons (cycloalkanes and alkylarenes) to alcohols and ketones with aqueous H2O2 in acetonitrile at room temperature is reported. Addition of a carboxylic acid increases the selectivity towards the ketone formation. Best results were obtained with ethylbenzene as substrate and acetic acid as additive, affording acetophenone as the main product.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据